Organoselenium-Catalyzed Oxidative C=C Bond Cleavage: ARelatively Green Oxidation of Alkenes into Carbonyl Compoundswith Hydrogen Peroxide

Tingting Wang,^†Xiaobi Jing,^†Chao Chen, and Lei Yu^*

School of Chemistry and Chemical Engineering, Yangzhou University

Abstract:A relatively green oxidative C=C bond cleavage of alkenes wasachieved by organoselenium-catalyzed alkene oxidation reaction in ethanol withhydrogen peroxide, affording carbonyl compounds under relatively mild

conditions. It is a new reaction style for the organoselenium-catalyzed oxidationof alkenes and largely contributes to the growingfield of organoseleniumcatalysis.

The Journal of Organic Chemistry,2017,82, 9342-9349. IF=4.849

文章链接:http://pubs.acs.org/doi/10.1021/acs.joc.7b01245