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Sheng‐Ping Guo and Huai‐Guo Xue published research achievements in angew
发布日期:2018-11-10 浏览次数: 字号:[ ]

A simple adduct from tin tetraiodide SnI4 and octasulfur S8, SnI4(S8)2 (1), is obtained employing a facile reaction. The combination of Sn4+ ions with d10 electron configuration, acentric SnI4 tetrahedra, and lonepair effects of S8, makes 1 a phasematchable infrared NLO crystal with a moderate secondharmonic generation (SHG) response and a very high laserinduced damage threshold (LIDT), which is well confirmed by the DFT calculations.

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