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俞磊教授在Scientific Reports上发表论文
发布日期:2017-12-12浏览次数:字号:[ ]

Solid-State 77Se NMR of Organoselenium Compounds through Cross Polarization Magic Angle Spinning (CPMAS) Method

Duo Wei,1 Mengting Han2 & LeiYu2

1 Testing Center, Yangzhou University

2 School of Chemistry and Chemical Engineering, Yangzhou University

Abstract: Characterization of selenium states by 77Se NMR is quite important to provide vital information for mechanism studies in organoselenium-catalyzed reactions. With the development of heterogeneous polymer-supported organoselenium catalysts, the solid state 77Se NMR comes to the spotlight. It is necessary to fgure out an advanced protocol that provides good quality spectra within limited time because solid state 77Se NMR measurements are always time consuming due to the long relaxation time and the relatively low sensitivity. Studies on small molecules and several novel polymer-supported organoselenium materials in this article showed that cross polarization (CP) method with the assistance of magic angle spinning (MAS) was more efcient to get high quality spectra than the methods by using single pulse (SP) or high power 1H decoupling (HPHD) combined with MAS. These results lead to a good understanding of the efect of the molecular structure, the heteronuclear coupling, the long-range ordering of the solid (crystal or amorphous), and the symmetry of 77Se on quality of their spectra.

 Scientific Reports, 2017, 7, 6376.  IF=4.259

文章链接:https://www.nature.com/articles/s41598-017-06892-8




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