师资队伍
 
导师简介 首页 >> 师资队伍
张扣林教授简介
发布日期:2012-10-03浏览次数:字号:[ ]

张扣林 博士 教授 硕士生导师

专业:无机化学
研究方向:配合物型功能材料
电话:13056348001
传真:0154-7975244
电子信箱: klzhang@yzu.edu.cn

教育经历:
1988, 9-1992, 7: 徐州师范大学化学系     化学教育专业
1992, 9-1995, 7: 南京大学化学化工学院   无机化学    专业  硕士
1999, 3-2002, 1: 南京大学化学化工学院   无机化学    专业  博士
2004, 1-2004, 7:  台湾  淡江大学化学系       博士后
2012, 11-2013, 5: 英国  华威大学化学系 (University of Warwick)      访问教授

工作经历:
1995.11 - 至今,扬州大学   化学化工学院 工作   教授,   化学化工学院
现任扬州大学化学化工学院   无机化学教研室主任 

研究领域和兴趣:
主要从事功能性配合物的设计、合成及性能的研究。
主要有三个方向:
1. 配合物型分子基磁性材料的设计、合成、结构及性质研究。主要目标为系统研究磁性与结构的关系,为能够定向设计并合成出具有特定功能的配合物型磁性材料打下坚实的基础。
2. 配合物型荧光材料的设计、合成、结构及性质的研究。主要目标为从分子设计的角度设计并合成出具有较好荧光性质的配合物,系统研究这些配合物的荧光性质与结构的关系,为能够定向设计并合成出较好荧光性能配合物型荧光材料打下基础。
3. 配合物型吸附材料的制备。主要目标为从分子设计的角度设计并合成出具有较好吸附性能的框架配位聚合物(MOFs),通过研究吸附性能与结构的关系,为能定向设计并合成配合物型吸附材料打下基础。

承担科研项目情况
(1). 主持了江苏省自然科学基金资助项目:P区元素Pb(II)框架配位聚合物的设计、合成及吸附性质。项目号:BK2012680, 2012, 7~2015, 7。
(2). 参与了国家自然科学基金资助项目:石墨烯三维结构自组装及其在电化学研究中的应用, 项目号:21273195,时间:2013.1~2016.12。

获奖情况
扬州大学优秀课堂教学质量三等奖 2006.1  2008.2
2002年 扬州大学  优秀青年骨干教师
2001年 南京大学  研究生光华奖学金

科研成果
1.  Y. Xu, J.-Q. Xu, K. -L. Zhang, X. Z. You, Keggin unit supported transition metal complexes: hydrothermal synthesis and characterization of [Ni(2,2’-bipy)3]1.5[PW12O40Ni(2,2’-bipy)2(H2O)]0.5H2O and [Co(1,10’-phen)3]1.5[PMo12O40Co(1,10’-phen)2(H2O)] 0.5H2O
Chem. Commum., (2000) 153-154.
2.  K. -L. Zhang*, Y.-J. Shi, S. Gao, Y. -D. Dai, X.-Z. You, Synthesis and characterization of a new iron(III) oxide cluster containing two different discrete [Fe3O] units: [Fe3O(O2CCH=CH---CH3)6(H2O)3][Fe3O(O2CCH=CH---CH3)7(H2O)2] (HO2CCH=CH---CH3)4(OH)(H2O). Inorg. Chem. Commum., 7 (2004) 584-587.
3.  K. -L. Zhang*, Z. Wang, H. Huang, X.-Z. You, Synthesis, crystal structure and magnetic properties of a novel dinuclear cobalt(II) complex based on the mixed N- and O-donor ligands: [Co2(pyrazine)(fumarato)2(H2O)8]•7H2O. J. of Mol. Struct., 693 (2004) 193-197.
4.  K. -L. Zhang *, Y. Xu, J. G. Lin, X.-Z. You, {[Cu(mal)(bipy)]•2H2O}n: a new one-dimensional ladder-like copper(II) complex based on the mixed N- and O-donor ligands with intrachain ferromagnetic interactions. J. of Mol. Struct., 1-3 (2004) 63-67.
5.  K. -L. Zhang*, Y. Xu, X.-Z. You, Synthesis, crystal and molecular structure and magnetic properties of an extended two-dimensional fumarato-bridged polymeric cobalt(II) complex [Co(l-fumarato)(c-methylpyridine)2(H2O)2]. Transition Met. Chem., 30 (2005) 376-379.
6.  K. -L. Zhang*, H.-W. Kuai, G. –W. Diao, Synthesis, characterization and crystal structure of a novel coordination compound based on the mixed N- and O- donor ligands exhibiting the metal ion-bridged ligand–ligand interaction: [Zn(2,2’-bipy)(Phmal)(H2O)].2H2O.
J. of Mol. Struct., 779/1-3 (2005) 11-15
7.  K. -L. Zhang*, H.-W. Kuai, W.-L. Liu, G. –W. Diao, Self assembly of a novel mixed-ligand hydrogen bonding three dimensional supramolecular network [Co(Phmal)(Him)4]
J. of Mol. Struct., 831 (2007) 114–118
8.  K. -L. Zhang*, N. Qiao, H.-Y. Gao, F. Zhou, M. Zhang, Self assembly of two novel three-dimensional supramolecular networks with blue photoluminescence  
Polyhedron, 26 (2007) 2461-2469.
9. K. -L. Zhang*, H.-Y. Gao, Z - C. Pan, W. Liang, G. –W. Diao, Preparation and characterization of two three-dimensionalmetal–organic photoluminescent supramolecular networks                Polyhedron, 26 (2007) 5177-5184.
10. K. -L. Zhang*, H.-Y. Gao, N. Qiao, F. Zhou, G. –W. Diao, Preparation and characterization of two novel three-dimensional supramolecular networks with blue photoluminescence             Inorg. Chim. Acta, 361 (2008) 153-160.
11. K. -L. Zhang*, F. Zhou; H.-Y. Gao; Z.-C. Pan; J.-G. Lin; Preparation and characterization of a   metal-organic three-dimensional framework based on isonicotinate [Pb(INA)2] (INA = isonicotinate, NC5H4-4-                    J. of Coord. Chem., 61(2008) 1494 - 1502.
12. K. -L. Zhang*, F. Zhou, L.-M. Yuan, G-W Diao, S. W. Ng, Synthesis and characterization of a novel photoluminescent three-dimensional metal–organic framework
 Inorg. Chim. Acta, 362 (2009) 2510–2514.
13. K. -L. Zhang*, W. Liang, Y. Chang, L.-M. Yuan, S. W. Ng, Syntheses, characterization and luminescent properties of two lead(II) fumarate metal-organic frameworks         Polyhedron, 28 (2009) 647-652.
14. K. -L. Zhang*, Y. Chang, C. T. Hou, R. Wu, G. W. Diao, S. W. Ng, Effect of N-donor auxiliary ligands on the engineering of crystalline architectures of a series of lead(II) complexes with 5-amino-2,4,6-triiodoisophthalic acid            CrystEngComm 12 (2010) 1194–1204.
15. K. -L. Zhang*, Z. -C. Pan, W. Liang, W. -L Liu, S. W. Ng, Synthesis and characterization of an energetic three-dimensional metal-organic framework with blue photoluminescence        Materials Letter 63 (2009) 2136-2138.
16. K. -L. Zhang*,Y. Chang, J.-B. Zhang, L.-M. Yuan, Y. Deng, G.-W. Diao, S. W. Ng Synthesis, crystal structures and characterization of four coordination polymers based on 5-amino-2,4,6-triiodoisophthalic acid           J. Solid. State Chem (2011) 1263-1272.
17. K. -L. Zhang*, Y. Chang, S. W. Ng Preparation and characterization of two supramolecular complexes with 5-amino-2,4,6-triiodoisophthalic acid under N-donor auxiliary ligand intervention                               Inorg. Chim. Acta, 368 (2011) 49–57.
18. K. -L. Zhang*, C. T. Hou, J.-J. Song, Y. Deng, L. Li, S. W. Ng, G.-W. Diao, Temperature and auxiliary ligand-controlled supramolecular assembly in a series of Zn(II)-organic frameworks: syntheses, structures and properties             CrystEngComm, 14 (2012) 590-600.
19. K. -L. Zhang*, Y. Chang, J.-B. Zhang, Y. Deng, T.-T. Qiu, L. Li, S. W. Ng, The cosolvent-dependent assembly of a family of three blue fluorescent lead(II)-coordination polymers with 5-amino- 2,4,6-tribromoisophthalic acid
CrystEngComm, 14 (2012) 2926-2935.
20 Y. Deng, C.-T.Hou, R.I.Walton, J. Tang, P. Zhu, K. -L. Zhang*, S. W. Ng Preparation, structural diversity and characterization of a family of Cd(II)-organic frameworks        
Dalton Trans., 2013, 42, 12468-12480.
21. W. Liang, Z. Zhong, Z.-C. Pan, Q.-H. Meng, Y. Deng, K. -L. Zhang*, Positional isomeric and N-donor auxiliary chelating ligand effect on engineering crystalline architectures of four lead(II) complexes with diverse fluorescent properties   
   J. Coord. Chem., 2013, 2802-2820.




打印本页 关闭窗口

版权所有:2000-2014  扬州大学化学化工学院

地址:扬州大学瘦西湖校区化学化工学院   邮编:225002

Produced By 大汉网络 大汉版通发布系统